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This should help
Scale of C Major, there are 7 notes :
C
D
E
F
G
A
B
Each is given a roman numeral depending on its place in the scale so
C- I (one)
D- II (two)
E- III (three)
F- IV (four)
G- V (five)
A- VI (six)
B- VII (seven)
So the chords are given their roman numeral based on this. E.g. a G Major chord is called chord V.
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