We really need to check the instruction manual of the amp, tell us what it is and I'll see if I can get any info... in the meantime...
From what you've said
1) The amp has an impedance selector switch for 16 or 8 ohm operation.
2) The amp has two identical sockets for speakers.
I would guess that you would use it like this:
One 16
ohm cab -> plug into either socket and set selector to 16 ohms
Two 16 ohm cabs -> plug each cab into each one of the sockets and set selector to 8 ohms (2 x 16 ohms in parallel wiring).
One 8 ohm cab -> plug into either and set selector to 8 ohms.
From your first post in stereo mode each side of your cab (A & B) has an impedance of 8
ohms. If you wanted to wire it up as if it was two independent cabs you'll need a 4 ohm switch on your amp. (When you have 2 cabs with the same impedance connected in parallel the combined impedance is HALF, as in the 2x16 example above).
Internally in mono mode the two halves of the cabs are wired in *series* which DOUBLES the impedance value(16 ohms).
If you really wanted to do what you want then I can give you the required changes to the cab wiring if that helps (you may need to get a soldering iron out!)
Still the best option, put the cab in mono and set the selector to 16 ohms and plug one lead from either socket to the mono input.
I hope this information helps, if not, ask again and I'll try to be clearer.
Jim